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华南理工大学化学与化工学院导师介绍 祝诗发

论坛   2013-03-19 12:03 【 】【我要纠错

姓名:祝诗发 性别:男 职称:副教授

学院:化学与化工学院 最后学历:博士

主要研究方向:有机合成、药物合成、金属有机、不对称有机合成

祝诗发,博士,副教授,硕士生导师。2001年6月本科毕业于湖南大学化学化工学院,同年考入中科院上海有机所硕博连读,导师朱仕正研究员,2006年6月获中科院上海有机所理学博士学位。同年9月赴美,先后在Syracuse University和University of South Florida从事博士后研究,主要研究方向为金属催化不对称有机合成。2009年5月,作为“海外优秀引进人才”进入华南理工大学化学与化工学院工作,2011年入选“教育部新世纪优秀人才支持计划”。已在J. Am. Chem. Soc., Angew. Chem. Int. Ed., Org. Lett., JOC等杂志上发表SCI 论文近30篇,申请中国专利7项,美国专利2项,目前主要从事过渡金属催化有机合成方面的研究工作。

主要学习工作经历:1997.09-2001.07 湖南大学化学化工学院,获学士学位

2001.09-2006.07 中国科学院上海有机所,获博士学位

2006.09-2007.01 Syracuse University化学系,博士后研究

2007.01-2008.12 University of South Florida化学系,博士后研究

2009.03-今 华南理工大学化学与化工学院海外优秀人才引进计划, 副教授

研究兴趣:有机合成;药物合成;金属有机化学;不对称有机合成;目前已发表文章近30篇,申请美国专利2篇、中国专利7篇

近年来主持的部分科研项目:1. 教育部新世纪优秀人才支持计划,(主持),2011.1-2013.12

2. 国家自然科学基金面上项目(主持),2012.1-2015.12;

3. 国家自然科学基金青年科学基金项目(主持),2010.1-2012.12

4. 广东省自然科学基金博士启动基金(主持),2009.10-2011.9;

5. 华南理工大学中央高校基本科研业务费(主持),2010.1-2012.12

6. 华南理工大学科研启动费(主持),2010.1-2012.12

7. 中科院上海有机所氟化学重点实验室开放基金 (主持), 2010.11-2012.10

8. 温州大学有机化学与皮革化工重中之重学科开放基金 (主持), 2010.11-2012.10

9 广东省自然科学基金团队项目(参与),2011.1-2013.12

10.国家科技支撑973项目(参与),2011.01-2015.08

代表文章1. Shifa Zhu*, Chao Wang, Lijuan Chen, Renxiao Liang, Yinfeng Yu, Huanfeng Jiang. Modular Approach for Synthesis of Vicinal Diamines Containing Axial Chiral 1,1′-Binaphthyl from 1,2-Diaminoethane by Pd-Catalyzed N-Arylation Reactions, Org. Lett. 2011, 13, 1146-1149.

2.

3. Shifa Zhu*, Lijuan Chen, Renxiao Liang, Chao Wang, Xiujun Wang, Yanwei Ren, Huanfeng Jiang. A practical system to synthesize the multiple-substituted 2,5-dihydrofuran by the intermolecular dipolar cycloaddition reactions involving acceptor/acceptor substituted diazo reagents. Tetrahedron 2011, 67, 5507-5515.

4. Shifa Zhu, Xue Xu, Jason Perman, Peter X. Zhang*. A General and Efficient Cobalt(II)-Based Catalytic System for Highly Stereoselective Cyclopropanation of Alkenes with alfa-Cyanodiazoacetates J. Am. Chem. Soc., 2010, 132, 12796-12799.

5. Shifa Zhu, Joshua V. Ruppel, Hongjian Lu, Lukasz Wojtas, Peter X. Zhang*. Cobalt-Catalyzed Asymmetric Cyclopropanation with Diazosulfones: Rigidification and Polarization of Ligand Chiral Environment via Hydrogen Bonding and Cyclization. J. Am. Chem. Soc., 2008, 130, 5042-5043. (Highlighted by SYNFACTS, 2008, 7, 720. and Angew. Chem. Int. Ed., 2009, 48, 850.)

6. Shifa Zhu, Jason Perman, X. Peter Zhang*. Acceptor/Acceptor-Substituted Diazo Reagents for Carbene Transfers: Cobalt-Catalyzed Asymmetric Z-Cyclopropanation of Alkenes with α-Nitro-Diazoacetates. Angew. Chem., Int. Ed., 2008, 47, 8460-8463. (Highlighted by SYNFACTS, 2009, 1, 74. and Angew. Chem. Int. Ed., 2009, 48, 850.)

7. Xin Cui, Xue Xu, Hongjian Lu, Shifa Zhu, Lukasz Wojtas, and X. Peter Zhang*, Enantioselective Cyclopropenation of Alkynes with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis. J. Am. Chem. Soc., 2011, 133, 3304-3307.

8. Shifa Zhu, Yuanxi Liao, Shizheng Zhu*. Transition-Metal-Catalyzed Formation of trans Alkenes via Coupling of aldehydes. Org. Lett. 2004, 6, 377-380.

9. Velusamy Subbarayan, Joshua V.Ruppel, Shifa Zhu, Jason A. Perman, X. Peter*. Zhang, Highly Asymmetric Cobalt-Catalyzed Aziridination of Alkenes with Trichloroethoxysulfonyl Azide (TcesN3). Chem. Commun. 2009, 28, 4266-4268.

10. Shifa Zhu, Yuanxi Liao, Shizheng Zhu*. The First Example of Catalytic Aziridination Mediated by Arsonium Ylides: Preparation of trans Pentafluorophenyl-Containing Aziridines, Synlett 2005, 1429-1432.

11. Shizheng Zhu*, Shifa Zhu, Guifang Jin, and Zhanting Li*. Strong Phenyl- perfluorophenyl ?-? Stacking Interactions and C-H…F-C Hydrogen Bonding Interactions in The Crystalline of Corresponding Aromatic aldimines. Tetrahedron Letters 2005, 46, 2713-2716.

12. Shifa Zhu, Chunhui Xing, Shizheng Zhu*. Stereoselective Preparation of Trifluoromethyl Containing 1,4-Oxathiolane Derivatives Through Ring Expansion Reaction of 1,3-Oxathiolanes, Tetrahedron 2006, 62, 829–832.

13. Shizheng Zhu*, Shifa Zhu, Yuanxi Liao. Rhodium(II)-Catalyzed Addition of 2-Diazo(fluoroalkyl)acetoacetates to Sulfides: a Simple Synthesis of Stable Sulfonium Ylides. Journal of Fluorine Chemistry 2004, 125, 1071–1076.

14. Shifa Zhu, Shizheng Zhu*, Yuanxi Liao, Chaofeng Huang, Zhanting Li*. Co-existing Intermolecular Halogen Bonding and Hydrogen Bonding in the Compound Trans-5,10-bis(1-bromodifluoroacetyl-1-ethoxycarbonyl-methylidene) Thianthrene. Chinese Journal of Chemistry 2004, 22, 896-898.

15. Shifa Zhu, Shizheng Zhu*. Rh2(OAc)4-Catalyzed Formation of trans Alkenes From the Reaction of Aldehydes with Perfluorophenyl Diazomethane Through Tellurium Ylide. Tetrahedron Lett. 2006, 47, 5897-5900.

16. Shifa Zhu, Wan Pang, Chunhui Xing, Shizheng Zhu, Lewis Base-Catalyzed Formation of α-Trifluoromethyl Alcohol from CF3SiMe3 and Carbonyl-Containing Compounds, Chinese Journal of Chemistry, 2007, 25, 2, 233-236.

17. Ruixin Zhu, Shifa Zhu, Junhong Zhou, Minbo Chen*. The Atoms in Molecules (AIM) Analysis of Abnormal Bonding of Several Fluorinated Supramolecular Systems, Acta Chimica Sinica 2006, 164, 191-197.

18. Wan Pang, Shifa Zhu, Huanfeng jiang and Shizheng Zhu*. Transition metal-catalyzed formation of CF3-substituted α,β-unsaturated alkene and the synthesis of α-trifluoromethyl substituted β-amino ester. Tetrahedron 2006, 62, 11760-11765.

19. Chunhui Xing, Xianfu Li, Shifa Zhu, Shizheng Zhu*. Synthesis of (E)-α-Per(poly)fluoroalkanesulfonyl- α,β-unsaturated Ketones and their Hetero Diels-Alder Reactions with Vinyl Ether, Tetrahedron Lett. 2006, 47, 4951-4955.

20. Hui wang, Shifa Zhu, Qinying Deng*, ShiZheng Zhu*. A facile synthesis of 4-gem-difluoromethylene β-lactam and its derivatives from BrCF2CF2Br, Journal of Fluorine Chemistry 2006, 127, 1195-1203.

21. Jun Li, Yongbin Han, Teresa B. Freedman, Shifa Zhu, Deborah J. Kerwood and Yan-Yeung Luk*, Utilizing the high dielectric constant of water: efficient synthesis of amino acid-derivatized cyclobutenones. Tetrahedron Lett. 2008, 49, 2128-2131.

22. Wan Pang; Shifa Zhu; Huanfeng Jiang; Shizheng Zhu*. A novel synthesis of 5-perfluorophenyl 4,5-dihydro-1H-pyrazoles in THF or water. Journal of Fluorine Chemistry 2007, 128, 1379-1384.

23. Wan Pang; Shifa Zhu; Huanfeng Jiang; Shizheng Zhu*. Rh(II)-catalyzed formation and rearrangement of trifluoroacetyl-containing sulfur ylides. Tetrahedron 2007, 63, 4543-4547.

24. Wan Pang; Shifa Zhu; Chunhui Xing; Nianhua Luo; Huanfeng Jiang; Shizheng Zhu*. Synthesis of stable arsonium and sulfur ylides fromperfluoroalkanesulfonyl diazocarbonyl compoundsand their X-ray diffraction analysis; Journal of Fluorine Chemistry 2008, 129, 343-348.

25. Weibing Liu, Huanfeng Jiang*, Shifa Zhu, et al., Hydroalkylation leading to heterocyclic compounds (Part 2): practical synthesis of polysubstituted 1,2,3,4-tetrahydropyridines through multicomponent reactions (MCRs) . Tetrahedron, 2009, 65(38), 7985.

26. Weibing Liu, Huanfeng Jiang*, Peng Zhou, Shifa Zhu DABCO-Induced [2+2+2] Cycloaddition Reaction of Ethyl Propiolate and Arylaldehydes to Synthesize 4-Aryl-4H-pyrans, Synlett 2009, 20, 3295.

27. Hua Cao, Huanfeng Jiang*, Ronghuan Mai, Shifa Zhu, Chaorong Qi, Silver-Catalyzed One-Pot Cyclization Reaction of Electron- Deficient Alkynes and 2-Yn-1-ols: An Efficient Domino Process to Polysubstituted Furans Adv. Synth. Catal. 2010, 352, 143.

28. Wan Pang, Shifa Zhu, Yong Xin, Huanfeng Jiang, Shizheng Zhu,Rh2(OAc)4 catalyzed formation of fluorine-containing polysubstituted furans from diazocompounds and aromatic alkynes, Tetrahedron, 2010, 66, 1261-1266.

29. Zhengwang Chen, Jinghao Li, Huanfeng Jiang, Shifa Zhu, Yibiao Li and Chaorong Qi, Silver-Catalyzed Difunctionalization of Terminal Alkynes: Highly Regio- and Stereoselective Synthesis of (Z)-β-Haloenol Acetates, Org. Lett. 2010, 12, 3262-3265.

书刊章节:

30. Shifa Zhu, X. Peter Zhang*, “Cobalt (II) Acetate”, in e-EROS Encyclopedia of Reagents for Organic Synthesis; Wiley-Interscience, 2009.

专利: 31. 轴手性咪唑盐化合物及其制备方法,祝诗发,王朝,专利申请号:CN201110008913.4

32. 轴手性邻二胺化合物及其制备方法,祝诗发,王朝,专利申请号:CN201110008898.3

33. 氮杂卡宾金络合物的制备方法,祝诗发,梁仁校,陈丽娟, CN201110107960.4

34. 氮杂卡宾铜络合物的制备方法,祝诗发,梁仁校,陈丽娟, CN201110107949.8

35. 氮杂卡宾银络合物的制备方法,祝诗发,梁仁校,陈丽娟, CN201110107958.7

36. 1-芳基-2-氟代芳基乙烯及其衍生物、其合成和应用。朱仕正、祝诗发,03129584

37. 含氟芳基亚胺化合物及其共晶化合物的合成和应用。朱仕正、祝诗发,00410089085.1

38. Cobalt-catalyzed asymmetric cyclopropanation with diazosulfones. X. Zhang, Shifa Zhu,PCT Int. Appl. (2009), WO 2009114849 A120090917 (美国专利,2009)

39. Peter X. Zhang, Shifa Zhu, Cobalt-Catalyzed Asymmetric Cyclopropanation of Alkene with ?-nitro-diazoacetates, U.S. Pat. Appl. Publ. (2010), US 2010081838 A120100401 (美国专利, 2010)

招生计划:硕士生:有机化学 名额: 2-3人

本科生:名额:2-3

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